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Two-dimensional carbon-based conductive materials with dynamically controlled asymmetric Dirac cones

机译:具有动态控制的不对称Dirac锥体的二维碳基导电材料

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摘要

The design of two dimensional graphene-type materials with an anisotropic electron flow direction in the X- and Y-axes opens the door for the development of novel electronic materials with multiple functions in nanoelectronics. In the present work, we have studied the electronic transport properties of a new family of 2D graphene-graphyne hybrids presenting conformationally free phenylethylene subunits. This system ensures two different conductive pathways that are perpendicular to each other: an acene nanoribbon subunit, in the X-axis, with graphene-type conduction, and a free to rotate phenylethylene subunit, in the Y-axis, in which the magnitude of the conduction depends dynamically on the corresponding torsion angle. Our calculations have confirmed that this system presents two different conduction pathways, which are related to the presence of asymmetric Dirac-type cones. Moreover, the Dirac cones can be dynamically modified in the presence of an external gate electrode, which is unprecedented in the literature
机译:在X和Y轴上具有各向异性电子流动方向的二维石墨烯型材料的设计为纳米电子中具有多种功能的新型电子材料的开发打开了大门。在目前的工作中,我们研究了呈现构象自由的苯基乙烯亚基的2D石墨烯-石墨烯杂化物新家族的电子输运性质。该系统可确保两个相互垂直的不同导电路径:在X轴上具有石墨烯型导电性的并苯纳米带亚基,以及在Y轴中可自由旋转的苯基乙烯亚基,其中传导动态地取决于相应的扭转角。我们的计算已经证实,该系统存在两种不同的传导途径,这与不对称Dirac型锥体的存在有关。此外,狄拉克锥可以在存在外部栅电极的情况下动态修改,这在文献中是前所未有的

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